✦ LIBER ✦

Platinum group metal functionalized phosphine complexes. Part 2. Phosphinoamide rhodium(I), iridium(I), palladium(II) and platinum(II) complexes

✍ Scribed by Tirumalasetty Satyanarayana; Kadaru Veera Reddy

Publisher: Springer
Year: 1994
Tongue: English
Weight: 588 KB
Volume: 19
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00139117

No coin nor oath required. For personal study only.

✦ Synopsis

Rhodium(I), iridium(I), palladium(lI) and platinum(II) complexes of the phosphinoamide ligands, Ph2PCH2CONHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized by using conductivity data, i.r., 1H and31P(H) n.m.r, spectral data. Reaction of the ligands with MCI(PPh3) 3 and MCI(CO)(PPh3)2 (M = Rh, Ir) in CH2C12 undcr rcflux lead to the formation of MCI(PPh3) 2-[Ph2PCH2C(O)NHR ] and MCI(CO)(PPha)[Ph2PCH2-C(O)HNR3 respectively. The reaction of either KzMC14 or cis-MC12(PPh3)2 affords complexes of the type cis-MC12[Ph2PCH2C(O)NHR] 2 (M= Pd, Pt). A similar product results even from the reaction of phosphinoamides with cis-platin. Possible structures are proposed for the complexes based on their physicochemical data.

📜 SIMILAR VOLUMES

Platinum group metal functionalized phos

Platinum group metal functionalized phosphine complexes. Part 1: Phosphinoamide ruthenium(II) complexes

✍ Tirumalasetty Satyanarayana; Kadaru Veera Reddy 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 737 KB

Three new bifunctional phosphinoamide ligands of the type Ph2PCH2C(O)NHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized. Their ruthenium(II) complexes prepared from two different precursors, RuC12-(DMSO)4 and RuClz(PPh3) 3, are of similar composition and correspond to the formula,

Cationic Palladium(II), Platinum(II), an

Cationic Palladium(II), Platinum(II), and Rhodium(I) Complexes as Acetalisation Catalysts

✍ Fabrizio Gorla; Luigi M. Venanzi 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 German ⚖ 384 KB

Complexes of long-chain bidentate ligand

Complexes of long-chain bidentate ligands: cobalt(II), nickel(II), rhodium(I) and iridium(I) with α, ω-bis(diphenylphosphino)alkanes, and palladium(II) and platinum(II) with 1, 10-bis(ethlthio)decane

✍ R.V. Parish; S.M. Razzoki 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 534 KB

Complexes of the ligands Ph2P(CH&PPh, (n = 8, 10, or 16) with cobalt(II), nickel(II), rhodium(I) and iridium(I), and of EtS(CH&SEt with palladium(I1) and platinum(I1) Experimental Spectroscopic data were obtained with the following spectrometers: infrared, Perkin-Elmer 621 and Beckman IR72; electron

Synthesis, 119Sn, 13C and 195Pt NMR stud

Synthesis, 119Sn, 13C and 195Pt NMR studies of five-coordinate rhodium(I), iridium(I) and platinum(II) complexes containing three trichlorostannate ligands

✍ M. Kretschmer; P.S. Pregosin; H. Rüegger 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 994 KB

Silver(I), palladium(II), platinum(II) a

Silver(I), palladium(II), platinum(II) and platinum (IV) complexes with isoorotate and 2-thioisoorotate ligands: synthesis, i.r. and n.m.r. spectra, thermal behaviour and antimicrobial activity

✍ Francisco Hueso-Ureña; Miguel N. Moreno-Carretero; Juan M. Salas-Peregrín; Gerar 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 716 KB

From the reaction of isoor0tic and 2-thioisoorotic acids with Ag x, Pd ~I, PtII and Pt w ions, twelve new complexes containing the uracil ligand in either mono-or dianionic forms have been isolated and studied by conductivity measurements, i.r. and n.m.r, spectroscopies, and by thermal methods (t.g.

Synthesis of sulphonated aminomethylphos

Synthesis of sulphonated aminomethylphosphines and some nickel(II), palladium(II), platinum(II) and rhodium(I) complexes. Crystal structure of [Et3NH][(Ph2PCH2)2N(CH2)2SO3]

✍ Osman Serindag; Raymond D. W. Kemmitt; John Fawcett; David R. Russell 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 404 KB

Synthesis of sulphonated aminomethylphosphines and some nickel(II), palladium(II), platinum(II) and rhodium(I) complexes. Crystal structure of [Et3NH] [(Ph2PCH2) 2 N(CH2)2SO3]