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Correcting reaction rates measured by saturation-transfer magnetic resonance spectroscopy

✍ Scribed by Refaat E. Gabr; Robert G. Weiss; Paul A. Bottomley

Book ID
108184876
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
765 KB
Volume
191
Category
Article
ISSN
1090-7807

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The spin-lock saturation transfer experiment introduced by B. Adams and L. Lerner (J. Magn. Reson. 96, 604-607, 1992) is analyzed in terms of the Bloch equations. It is shown that the T1rho relaxation of the solvent is introduced in the decay of the exchangeable protons under conditions of relativel