Nitrogen-15 nuclear magnetic resonance spectroscopy. Differential rates of nitrogen-hydrogen proton-transfer reactions in phenylhydrazine
✍ Scribed by Yavari, Issa; Roberts, John D.
- Book ID
- 120379620
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 359 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Nitrogen-15-hydrogen coupling constants between "N-labeled oximes and a-C-protons, "J(l"NH), of two series of E/Z ketoximes were studied in CCl,, CDCI,, CF,COOH, and DMSO-4. 15N-substituted-methyl phenyl ketoximes constituted the first series and 15N-substituted-methyl 2-quinoxalinyl ketoximes the s
## Abstract The proton‐coupled nitrogen‐15 NMR spectra of hydrazinecarbothioamide and 4‐methylhydrazinecarbothioamide have been taken at the natural‐abundance level in neutral, basic and acidic solutions at 25°C. The NH proton‐exchange reactions of the hydrazino‐NH~2~ groups in both compounds were