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Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

✍ Scribed by Mahbod Morshedi; Mehdi Amirnasr; Smail Triki; Aliakbar Dehno Khalaji


Publisher
Springer
Year
2010
Tongue
English
Weight
252 KB
Volume
41
Category
Article
ISSN
1572-8854

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## Abstract An exploration of the Cu(I)‐L system under hydrothermal conditions, has led to the isolation of a novel framework [Cu(I)(L)]~n~ (**1**) (L = bis(3,3‐dimethyl‐4,4‐dihydro‐1H‐pyrazol‐4‐yl)methane). Single‐crystal X‐ray analysis reveals that it crystallizes in the monoclinic, space group C

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The reaction of CuC1 or CuX 2 (X = C1 or NO3) with NPm (diphenylphosphinodiphenylaminomethane) yields molecular P-bonded copper(I) complexes of general formula CuL2X. These complexes are isostructural. For both complexes the coordination geometry around the copper atom is almost trigonal planar and