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Copper-Mediated Coupling of 1,1-Dibromo-1-alkenes with Nitrogen Nucleophiles: A General Method for the Synthesis of Ynamides

✍ Scribed by Alexis Coste; Ganesan Karthikeyan; François Couty; Gwilherm Evano

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
406 KB
Volume
121
Category
Article
ISSN
0044-8249

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Copper-Mediated Coupling of 1,1-Dibromo-
Copper-Mediated Coupling of 1,1-Dibromo-1-alkenes with Nitrogen Nucleophiles: A General Method for the Synthesis of Ynamides
✍ Alexis Coste; Ganesan Karthikeyan; François Couty; Gwilherm Evano 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB 👁 1 views

## Abstract Mild reaction conditions are the advantage of the title reaction, which allows straightforward entry to a variety of ynamides starting from readily available 1,1‐dibromo‐1‐alkenes, which act as attractive alkynylating agents (see scheme; EWG=electron‐withdrawing group, DMF=__N__,__N__‐d

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