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ChemInform Abstract: Decarbonylative Radical Cyclization of α-Amino Selenoesters upon Electrophilic Alkenes. A General Method for the 6-Azabicyclo[3.2.1]octane Synthesis.

✍ Scribed by Josefina Quirante; Xavier Vila; Carmen Escolano; Josep Bonjoch

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A New Method to Gen
ChemInform Abstract: A New Method to Generate α-Aminoalkyl Radicals: Treatment of Methyl α-Amino Selenoesters with Hydride Reagents. Synthesis of 6-Azabicyclo(3.2.1)octanes by Radical Cyclization.
✍ J. QUIRANTE; C. ESCOLANO; J. BONJOCH 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

A New Method to Generate α-Aminoalkyl Radicals: Treatment of Methyl α-Amino Selenoesters with Hydride Reagents. Synthesis of 6-Azabicyclo(3.2.1)octanes by Radical Cyclization. -α-Amino selenoesters on heating with Bu3SnH or Tms3SiH undergo decarbonylation to afford intermediate α-aminoalkyl radical