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Copper catalyzed oxidative alkylation of sp3 C–H bond adjacent to a nitrogen atom using molecular oxygen in water

✍ Scribed by Baslé, Olivier; Li, Chao-Jun

Book ID
120614252
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
204 KB
Volume
9
Category
Article
ISSN
1463-9262

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✍ Hiromasa Mitsudera; Chao-Jun Li 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 349 KB

Copper-catalyzed trifluoromethylation via oxidative sp 3 C-H activation at the a-position of nitrogen in tetrahydroisoquinoline derivatives using DDQ and Ruppert-Prakash reagent has been successfully achieved. The reaction of various amines gave the corresponding trifluoromethylated products in 15-9