Copolymerization of ethylene with higher linear α-olefins—reactivity ratios
✍ Scribed by Kissin, Y. V. ;Beach, D. L.
- Book ID
- 105335117
- Publisher
- John Wiley and Sons
- Year
- 1984
- Weight
- 380 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0360-6376
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## Abstract Ethylene was polymerized at 15,000–25,000 psi at 130–220°C. with free‐radical initiators in the presence of 0–10% of C^14^‐labeled propylene, butene‐1, and octene‐1. Polymer composition was determined by scintillation counting. Molecular weight measurements and polymer unsaturation as d
Experimental determinations of reactivity ratios for heterogeneous copolymerizations are highly dependent upon experimental conditions such as different solubilities and composition drift of the comonomers due to their different reactivities. An integrated form of the copolpnerization equation is pr