The copolymerization of propylene/ethylene and terpolymerization of propylene/ethylene/␣-olefins using long-chain ␣-olefins such as 1-octene and 1-decene have been carried out using EtInd 2 ZrCl 2 //methylaluminoxane. High concentrations of propylene and low concentrations of ␣-olefins (near 2 mol %
The copolymerization of propylene with higher, linear α-olefins
✍ Scribed by Albert J. Van Reenen; Robert Brull; Udo M. Wahner; Helgard G. Raubenheimer; Ronald D. Sanderson; Harald Pasch
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 173 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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## Abstract Copolymerizations of propene with higher α‐olefins including 1‐butene, 1‐hexene, 1‐octene, 1‐dodecene and 1‐hexadecene were carried out with an isospecific metallocene catalyst (Et[Ind]~2~HfCl~2~/methylaluminoxane) at 30°C in toluene. ^13^C NMR analysis showed that all products obtained
## Abstract This work deals with a novel glass fiber surface modification and subsequent metallocenic propylene polymerization onto it. Experimental results are presented on methylaluminoxane (MAO) fixation at the fiber surface, followed by propylene–α‐olefin graft copolymerization catalyzed by EtI
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