Ethylene homopolymerization and ethylene/␣-olefin copolymerization were carried out using unbridged and 2-alkyl substituted bis(indenyl)zirconium dichloride complexes such as (2-MeInd) 2 ZrCl 2 and (2-BzInd) 2 ZrCl 2 . Various concentrations of 1-hexene, 1-dodecene, and 1-octadecene were used in ord
✦ LIBER ✦
Copolymerization of ethylene and 1-octadecene with the Cp2ZrCl2/MAO and Cp2HfCl2/MAO catalyst systems
✍ Scribed by Jari Koivumäki
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 299 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0170-0839
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It is demonstrated that the catalyst system bis(pentamethylcyclopentadienyl)-zirconium dichloride (Me 5 Cp) 2 ZrCl 2 -methylaluminoxane (MAO) is able to produce random copolymers of ethene and 1-hexene. The 1-hexene incorporation in the copolymers is extremely small. Even in the case of a molar rati