Properties of ethylene/1-octene, 1-tetradecene and 1-octadecene copolymers obtained with Cp2ZrCl2/MAO catalyst: effect of composition and comonomer chain length
✍ Scribed by Jari Koivumäki
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 305 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
The copolymerization of ethylene and 1-octadecene using a bridged metallocene was studied in order to observe the effect of the comonomer on the catalytic activity. A noticeable increase in activity is seen as the concentration of 1-octadecene in the reaction medium increases. 13 C NMR analysis show
## Abstract Polymerization of ethylene and copolymerizations of ethylene with 1‐octene and oligoethylene having a vinyl end group were conducted with Cp~2~ZrCl~2~ and [(C~5~Me~4~)SiMe~2~N(t‐Bu)]TiCl~2~^a^ as catalysts, and the structures of the resulting polymers were analyzed in detail. The Cp~2~Z