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Copolymerization of ethylene and 1-hexadecene with Cp2ZrCl2-methylaluminoxane catalyst

✍ Scribed by J. Koivumäki; J.V. Seppälä

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
155 KB
Volume
34
Category
Article
ISSN
0032-3861

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📜 SIMILAR VOLUMES

Efficient Molecular Weight Control with
Efficient Molecular Weight Control with Trialkylaluminum in Ethylene/Norbornene Copolymerization by [Ph2C(Flu)(3-MeCp)]ZrCl2/Methylaluminoxane Catalyst
✍ Tomoyuki Tada; Zhengguo Cai; Yuushou Nakayama; Takeshi Shiono 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 189 KB

## Abstract Ethylene/norbornene copolymerizations were conducted with [Ph~2~C(Flu)(3‐RCp)]ZrCl~2~ [R: Me (1) or Me~3~Si (2)], which give alternating EN copolymers. The activity of 1 in the absence of R~3~Al was approximately twice that of 2 and increased further upon addition of R~3~Al. Et~3~Al inc