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Reversible and irreversible deactivation of propene polymerization using homogeneous Cp2ZrCl2/methylaluminoxane Ziegler—Natta catalysts

✍ Scribed by David Fischer; Rolf Mülhaupt


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
333 KB
Volume
417
Category
Article
ISSN
0022-328X

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✍ Friedrich G. Sernetz; Rolf Mülhaupt; Robert M. Waymouth 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 558 KB

## Abstract Styrene was copolymerized with ethylene using Me~2~Si(Me~4~Cp)(__N‐tert__‐butyl)TiCl~2~/methylaluminoxane (Me = methyl, Cp = cyclopentadienyl) varying monomer concentration, styrene/ethylene molar ratio and polymerization temperature. Increasing styrene or decreasing ethylene concentrat