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Coordination Sphere Tuning of the Electron Transfer Dissociation Behavior of Cu(II)–Peptide Complexes

✍ Scribed by Jia Dong; Richard W. Vachet

Book ID: 107700834
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 458 KB
Volume: 23
Category: Article
ISSN: 1044-0305
DOI: 10.1007/s13361-011-0299-1

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## Abstract Transition metal cations Co^2+^, Ni^2+^ and Zn^2+^ form 1 : 1 : 1 ternary complexes with 2,2′‐bipyridine (bpy) and peptides in aqueous methanol solutions that have been studied for tripeptides GGG and GGL. Electrospray ionization of these solutions produced singly charged [Metal(bpy)(pe