## Abstract Electron‐induced dissociations of gas‐phase ternary copper‐2,2′‐bipyridine complexes of Gly‐Gly‐Gly and Gly‐Gly‐Leu were studied on a time scale ranging from 130 ns to several milliseconds using a combination of charge‐reversal (^+^CR^−^) and electron‐capture‐induced dissociation (ECID)
Energetics and Dynamics of Electron Transfer and Proton Transfer in Dissociation of Metal III (salen)−Peptide Complexes in the Gas Phase
✍ Scribed by Laskin, Julia; Yang, Zhibo; Chu, Ivan K.
- Book ID
- 126959417
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 346 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Transition metal cations Co^2+^, Ni^2+^ and Zn^2+^ form 1 : 1 : 1 ternary complexes with 2,2′‐bipyridine (bpy) and peptides in aqueous methanol solutions that have been studied for tripeptides GGG and GGL. Electrospray ionization of these solutions produced singly charged [Metal(bpy)(pe
The beginning of the twentieth century saw the development of new theories of acidity and basicity, which are currently well accepted. The thermochemistry of proton transfer in the absence of solvent attracted much interest during this period, because of the fundamental importance of the process. Ne