Outer-sphere electron-transfer between horse heart cytochrome c and anionic Cu(ii/i) complexes. Evidence for precursor formation and coordination sphere reorganization for electron transfer

Kinetics and Mechanism of the Outer-Sphe

Kinetics and Mechanism of the Outer-Sphere Oxidation of Horse-Heart Cytochrome c by an Anionic Chromium(v) Complex – Kinetic Evidence for Precursor Formation and a Late Electron-Transfer Transition State

✍ Manuela Körner; Rudi van Eldik 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 2 views

Keywords: Cytochrome c / Chromium(v) / Saturation kinetics / Separation of K and k ET / Volume profile / Kinetics The irreversible outer-sphere electron-transfer reaction High-pressure experiments were performed at two different pH values. The kinetic (stopped-flow) and thermodynamic between trans-