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Coordination chemistry of [P2Se6]4? in molten fluxes. Isolation of the structurally complex KMP2Se6(M = Sb, Bi)

✍ Scribed by McCarthy, Timothy J.; Kanatzidis, Mercouri G.


Book ID
120818958
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
277 KB
Volume
9
Category
Article
ISSN
0022-4936

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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 Β°C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 Β°C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst