Coordination and oxidation of sulphur and nitrogen oxides by complexes of some platinum metals
β Scribed by J.J. Levison; S.D. Robinson
- Publisher
- Elsevier Science
- Year
- 1968
- Weight
- 99 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
and MPt,O, (M = Mn, Co, Cd). An enumeration of the allowed Raman modes is made for all of these oxides except Pt,O, , for which the structure is unknown. Polarization measurements allow symmetry species assignments to be made for the lines from a-PtO, and PtCoO, , and a likely assignment of the line
Reduction of NO in 2-8 M HCIO, and 2 M HCI at E a 0.35 V on platinized and smooth platinum electrodes is a diffusion-controIled process. On freshly activated electrodes the reduction in this potential region involves one-elatron reaction to form N,O, as well as multiple-electron reduction yielding N
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## Abstract Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogenβnitrogen bonds and N~2~ cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido de