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Conversion of N,N′-bis(tert-butoxycarbonyl)guanidines to N-(N′-tert-butoxycarbonylamidino)ureas
✍ Scribed by Hugues Miel; Sylvain Rault
- Book ID
- 108386558
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 224 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The total dewotection of N~Ubis-Boc guanidines using SnCI4 woceeds smoothly in ethyl acetate at room tempemtme and leads to the easily isolable cone~n~g guanidinlum chlorides.
Total Deprotection of N,N'-Bis(tert-butoxycarbonyl)guanidines Using SnCl 4 . -An excess of SnCl 4 is found to be effective for the high yielding total deprotection of bis-Boc guanidines (I) (11 examples). -
The title compound, C 11 H 20 O 4 N 2 S, has a planar skeleton and its crystal structure is stabilized by extensive intermolecular (NÐHÁ Á ÁS) and intramolecular (NÐHÁ Á ÁO and CÐHÁ Á ÁO) hydrogen-bonding interactions.