Conversion of aldehydes to nitriles via photochemical reaction
β Scribed by Roger W. Binkley
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 90 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The synthesis of nitriles is a process which, in the past, has frequently required quite n vigorous reaction conditions'.
In recent years, however, interest has arisen in examining milder methods for nitrile synthesis 3-5 . As a contribution to the solution of this problem of reaction conditions, we wish to report our results on a two-step sequence employing a photochemical process which achieves an aldehyde to nitrile conversion under extremely mild conditions6.
π SIMILAR VOLUMES
Ab~mrt: O-Arylcarbamoylated hydroxylamine tosylate reacts with aldehydes at room temperature to give the corresponding O-earbamoylated oximes. The reaction of earbamoylated hydroxylamine with aromatic aldehydes in THF or in toluene at reflux affords the corresponding nitriles and anilinium tosylate
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