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Convergent Synthesis of Peptide Conjugates Using Dehydroalanines for Chemoselective Ligations

✍ Scribed by Zhu, Yantao; van der Donk, Wilfred A.

Book ID
126184916
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
54 KB
Volume
3
Category
Article
ISSN
1523-7060

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An oligonucleotide was functionalized on the solid-phase by a tartaramide moiety, which could be converted efficiently in solution into a glyoxylyl group following a mild periodic oxidation. The glyoxylyl-oligonucleotide was found to be very stable upon storage and was successfully engaged in hydraz