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Convergent Highly Stereoselective Preparation of the C12−C24 Fragment of Macrolactin A

✍ Scribed by Bonini, Carlo; Chiummiento, Lucia; Pullez, Maddalena; Solladié, Guy; Colobert, Françoise

Book ID
115528867
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
151 KB
Volume
69
Category
Article
ISSN
0022-3263

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Synthesis of the C7–C24 fragment of (−)-Macrolactin F
✍ Roberta A. Oliveira; Juliana M. Oliveira; Luis H.S. Rahmeier; Joao V. Comasseto; 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 163 KB

An enantioselective and convergent synthesis of the C7-C24 fragment of Macrolactin F was achieved from four main fragments. A hydrotelluration/transmetalation sequence was used to install the E,Z diene present in the molecule, while a hydrozirconation/transmetalation sequence was used to connect two