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Studies on the total synthesis of macrolactin A. A stereoselective synthesis of the C3–C13 and C14–C24 fragments

✍ Scribed by Shukun Li; Rui Xu; Donglu Bai

Book ID
108379720
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
123 KB
Volume
41
Category
Article
ISSN
0040-4039

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✍ Roberta A. Oliveira; Juliana M. Oliveira; Luis H.S. Rahmeier; Joao V. Comasseto; 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 163 KB

An enantioselective and convergent synthesis of the C7-C24 fragment of Macrolactin F was achieved from four main fragments. A hydrotelluration/transmetalation sequence was used to install the E,Z diene present in the molecule, while a hydrozirconation/transmetalation sequence was used to connect two