## Abstract An improved classic Strecker synthesis was elaborated leading to racemic homopropargylglycine (Hpg) in 61% overall yield, while an asymmetric Strecker reaction produced Hpg and the higher homolog 2βaminoheptβ6βynoic acid in significantly higher yields and over 80% ee. Copyright Β© 2008 E
β¦ LIBER β¦
Convenient syntheses of hydroindans and hydronaphthalenes
β Scribed by Chou, Ta-Shue; Tso, Hsi-Hwa; Chang, Lee-Jean
- Book ID
- 118025896
- Publisher
- The Royal Society of Chemistry
- Year
- 1985
- Tongue
- English
- Weight
- 153 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0022-4936
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Absrracr : Dihpropyl ( macapomethyl) pbosphonace was easily prepad by the reduction of S-merliyl phosphono-ditbioestawith~Umborohydride,beacedundafluXofacetonieile.'Ibephosphonatccabsnmn . g-from eg s-ally1 St&i& denvent a [3Jl sigmatropic shin and ted to diisopmpyl (atlyt mercapto methyl)