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Convenient syntheses of homopropargylglycine

✍ Scribed by Shouliang Dong; Lars Merkel; Luis Moroder; Nediljko Budisa

Book ID: 105359701
Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 86 KB
Volume: 14
Category: Article
ISSN: 1075-2617
DOI: 10.1002/psc.1065

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✦ Synopsis

Abstract

An improved classic Strecker synthesis was elaborated leading to racemic homopropargylglycine (Hpg) in 61% overall yield, while an asymmetric Strecker reaction produced Hpg and the higher homolog 2‐aminohept‐6‐ynoic acid in significantly higher yields and over 80% ee. Copyright © 2008 European Peptide Society and John Wiley & Sons, Ltd.

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