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Convenient Method for Epoxidation of Alkenes Using Aqueous Hydrogen Peroxide

✍ Scribed by Tse, Man Kin; Klawonn, Markus; Bhor, Santosh; Döbler, Christian; Anilkumar, Gopinathan; Hugl, Herbert; Mägerlein, Wolfgang; Beller, Matthias

Book ID
120018377
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
87 KB
Volume
7
Category
Article
ISSN
1523-7060

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Convenient asymmetric (salen)Mn(III)-cat
Convenient asymmetric (salen)Mn(III)-catalyzed epoxidation of unfunctionalized alkenes with hydrogen peroxide using carboxylate salt cocatalysts
✍ Pekka Pietikäinen 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 511 KB

Asymmetric epoxidation of unfunctionalized alkenes is reported using chiral (salen)Mn(III) complexes 1-$ together with a carboxylate salt cocatalyst in the presence of either aqueous H202 or anhydrous urea-H202 adduct as oxidant. Several simple soluble salts (acetates, formates, benzoates) were stud