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Cyclopentadienyl–Silsesquioxane Titanium Complexes: Highly Active Catalysts for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide

✍ Scribed by Ventura, María; Mosquera, Marta E. G.; Cuenca, Tomás; Royo, Beatriz; Jiménez, Gerardo


Book ID
111871185
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
555 KB
Volume
51
Category
Article
ISSN
0020-1669

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## Abstract A modular synthesis for chiral and non‐symmetrical salalen ligands (i.e., mono‐reduced salens), carrying an imine and an amine functionality has been developed. The ligands can be assembled __in situ__ by Schiff base formation of an __N__‐(2‐hydroxybenzyl)diamine with a salicylic aldehy