A Simple and Versatile Method for Alkene Epoxidation Using Aqueous Hydrogen Peroxide and Manganese Salophen Catalysts.
β Scribed by Shih-Yuan Liu; Daniel G. Nocera
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 24 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A modular synthesis for chiral and nonβsymmetrical salalen ligands (i.e., monoβreduced salens), carrying an imine and an amine functionality has been developed. The ligands can be assembled __in situ__ by Schiff base formation of an __N__β(2βhydroxybenzyl)diamine with a salicylic aldehy
## Abstract A simple catalytic system that uses commercially available manganese(II) perchlorate as the catalyst and peracetic acid as the oxidant is found to be very effective in the epoxidation of aliphatic terminal alkenes with high product selectivity at ambient temperature. Many terminal alken