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Convenient General Asymmetric Synthesis of Roche Ester Derivatives through Catalytic Asymmetric Hydrogenation: Steric and Electronic Effects of Ligands

✍ Scribed by Cyrielle Pautigny; Séverine Jeulin; Tahar Ayad; Zhaoguo Zhang; Jean-Pierre Genêt; Virginie Ratovelomanana-Vidal

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
235 KB
Volume
350
Category
Article
ISSN
1615-4150

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ChemInform Abstract: Convenient General
ChemInform Abstract: Convenient General Asymmetric Synthesis of Roche Ester Derivatives Through Catalytic Asymmetric Hydrogenation: Steric and Electronic Effects of Ligands.
✍ Cyrielle Pautigny; Severine Jeulin; Tahar Ayad; Zhaoguo Zhang; Jean-Pierre Genet 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Asymmetric Synthesis of the Roche Ester
Asymmetric Synthesis of the Roche Ester and its Derivatives by Rhodium-INDOLPHOS-Catalyzed Hydrogenation
✍ Jeroen Wassenaar; Mark Kuil; Joost N. H. Reek 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 178 KB 👁 1 views

## Abstract (__S__)‐3‐Hydroxy‐2‐methylpropionate, known as the Roche ester, and several of its derivatives were successfully synthesized through asymmetric rhodium‐catalyzed hydrogenation, using INDOLPHOS (diisopropyl{1‐[(__S__)‐3,5‐dioxa‐4‐phosphacyclohepta[2,1‐__a__;3,4‐__a′__]dinaphthalen‐4‐yl]‐