Protected glycals, derived from mono-, di-and tri-saccharides, were easily and efficiently converted into the corresponding 2-dcoxy-sugars, by reaction with mercoric(ID acetate/sodium borohydride in a polar solvent at 0 Β°C. The mild and non acidic reaction conditions permit the survival of acid-labi
Convenient and stereospecific synthesis of deoxy sugars. Reductive displacement of trifluoromethylsulfonates
β Scribed by Barrette, Ernie Paul; Goodman, Leon
- Book ID
- 126818836
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 483 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Condensation of Z-deoxy-~-ribose with nitromethane gave, after deionization, a syrupy mixture of epimeric l-nitro-1,3-dideoxy-hexitols. Acid hydrolysis under Nef reaction conditions produced a mixture of 3-deoxy-~-glucose and 3-deoxy-m mannose, separable by cellulose chromatography or fractional cry