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ChemInform Abstract: Mercuration-Reductive Demercuration of Glycals: A Mild and Convenient Entry to 2-Deoxy-Sugars.

✍ Scribed by E. BETTELLI; P. CHERUBINI; P. D'ANDREA; P. PASSACANTILLI; G. PIANCATELLI

Book ID
101865713
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Protected glycals, derived from mono-, di-and tri-saccharides, were easily and efficiently converted into the corresponding 2-dcoxy-sugars, by reaction with mercoric(ID acetate/sodium borohydride in a polar solvent at 0 Β°C. The mild and non acidic reaction conditions permit the survival of acid-labi

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