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Mercuration-reductive demercuration of glycals: A mild and convenient entry to 2-deoxy-sugars

✍ Scribed by Enzo Bettelli; Paola Cherubini; Piero D'Andrea; Pietro Passacantilli; Giovanni Piancatelli

Book ID
104208579
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
418 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

Protected glycals, derived from mono-, di-and tri-saccharides, were easily and efficiently converted into the corresponding 2-dcoxy-sugars, by reaction with mercoric(ID acetate/sodium borohydride in a polar solvent at 0 °C. The mild and non acidic reaction conditions permit the survival of acid-labile groups, such as silyl ethers.

📜 SIMILAR VOLUMES

ChemInform Abstract: Mercuration-Reducti
ChemInform Abstract: Mercuration-Reductive Demercuration of Glycals: A Mild and Convenient Entry to 2-Deoxy-Sugars.
✍ E. BETTELLI; P. CHERUBINI; P. D'ANDREA; P. PASSACANTILLI; G. PIANCATELLI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

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