๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions

โœ Scribed by Kano, Taichi; Hayashi, Yumi; Maruoka, Keiji

Book ID
120260804
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
315 KB
Volume
135
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Construction of chiral quaternary carbon
Construction of chiral quaternary carbon centers by asymmetric alkylation of achiral lithium enolates mediated by chiral tetradentate ligands: Stoichiometric and catalytic approaches
โœ Yasuhiro Yamashita; Kazunori Odashima; Kenji Koga ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 217 KB

Enantioselective asymmetric alkylation of achiral lithium enolates mediated by chiral tetradentate amine ligands is achieved to give chiral quaternary carbon centers. Turnover of a chiral tetradentate amine in the presence of an achiral bidentate amine during the reaction is also realized.