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Conjugated acylation of alkylacetylenes by cationoid reagents in the presence of aromatic hydrocarbons

โœ Scribed by A. A. Shchegolev; V. A. Smit; S. A. Khurshudyan; V. A. Chertkov; V. F. Kucherov

Book ID
112488390
Publisher
Springer
Year
1977
Tongue
English
Weight
586 KB
Volume
26
Category
Article
ISSN
1573-9171

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โœ A.A. Schegolev; W.A. Smit; G.V. Roitburd; V.F. Kucherov ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

We have recently described the successful use of carbocationic reagents in electiophilic additions to the triple bond and demonstrated that vinyl cations, presumably formed as intermediates in these reactions, could be trapped even by such poor nucleophilic solvents as nitromethane /I/ or chlorobenz