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ChemInform Abstract: Catalytic Pinacol Coupling in the Presence of Acylating Reagent.

โœ Scribed by Toshikazu Hirao; Hiroki Takeuchi; Akiya Ogawa; Hidehiro Sakurai

Publisher
John Wiley and Sons
Year
2001
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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Reductive Pinacol Coupling of Aromatic Carbonyl Compounds Catalytic in Chromium(II). -The pinacol reductive coupling is effectively catalyzed by Cr(II) salts co-reduced with Mn powder. The reaction rate and diastereoselectivity are predominantly controlled by the trialkylsilyl chloride used for acti