Conjugate addition of amides to α,β-unsaturated esters by CsF-Si(OEt)4 system
✍ Scribed by Kyo Han Ahn; Seok Jong Lee
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 273 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The conjugate addidon of amides to cx&unsawared esters proceeds &kiendy with an equimolar amount of Si(OEr)d and a catalytic wnount of CsF w crfford the corresponding N-substituted amides.
📜 SIMILAR VOLUMES
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Free radica2 addition of either methyl bromoacetate or iodoacetamide to an cl, B-unsaturated ester gave the 4-substituted ghtarate or glutarimide respectively, whereas the radical cycZisation of N-bromoacetyl crotonamide gave the &substituted succinimide.