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Conformationally Driven Asymmetric Induction of a Catalytic Dendrimer

✍ Scribed by Yu, Jianfeng; RajanBabu, T. V.; Parquette, Jon R.

Book ID
127013040
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
820 KB
Volume
130
Category
Article
ISSN
0002-7863

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The axial conformation of an aromatic tertiaryamidegroupmaybe powerfully influenced byanadjacent stereogenic centre. Becausethe amide axis can atso control tbejorrmuion of new chiralcentres, theamidecanactas a "relaycentre"for the transmission of stereochemical information. Confirmational interlocki