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First example of high asymmetric induction at the “pseudo-micellar” interface of a chiral amphiphilic dendrimer

✍ Scribed by A. Schmitzer; E. Perez; I. Rico-Lattes; A. Lattes


Book ID
104261125
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
197 KB
Volume
40
Category
Article
ISSN
0040-4039

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Organic reactions at high pressure. Asym
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Asymmetric induction in the high pressure (15 kbar, 1.5 GPa) Duels-Alder reactlon of e-benzoqulnone with choral 2,4-pentadienoic acid derivatives is evaluated The reactions afford 4a,5,8,8a-tetrahydro-1,4-naphthalenedlones in up to 50% enantlomenc excess.