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Conformational Properties of (Z,Z)-, (E,Z)-, and (E,E)-Cycloocta-1,4-dienes

✍ Scribed by Issa Yavari; Hassan Kabiri-Fard; Shahram Moradi


Publisher
Springer Vienna
Year
2002
Tongue
English
Weight
93 KB
Volume
133
Category
Article
ISSN
0026-9247

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(Z,E,E)-humulene. Conformational analysi
✍ Haruhisa Shirahama; Grudial S. Arora; Eiji Ōsawa; Takeshi Matsumoto πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 277 KB

Geometries and populations for four possible conformers of (L,i,E)-humulene (,j) were obtained by molecular mechanics calculations. Treatment of L with mercury salt gave 3,7-epoxy-3,6-secoprotoilludane (2) and 9,10-epoxide of 1 afforded tetramethylbicyclo[7.2.0]undecadienols (l,O,lJ) on treatment wi