Ab InitioStudy of Conformational Properties of (Z,Z)-, (E,Z)-, and (E,E)-Cyclonona-1,5-dienes
β Scribed by Issa Yavari; Rahebeh Amiri; Mina Haghdadi
- Publisher
- Springer Vienna
- Year
- 2004
- Tongue
- English
- Weight
- 235 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0026-9247
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π SIMILAR VOLUMES
3Z,6E)-l-Bromododeca-3,6-diene, a common intermediate in the synthesis of labelled 12t linoleic acid and 14t arachidonic acid, was obtained from (E)-3-nonyl-l-ol, in four steps, via conventional functional manipulations. Cross-coupling of this bromododecadiene with the Grignard reagent of l-chloro-5
3Z,6Z,9Z,12E)-Pentadecatetraenal, a common intermediate in the synthesis of methyl A l7t EPA and methyl A I9t DHA, was obtained by copper(I)-catalyzed coupling between the Grignard reagent of I, 1-diethoxy-3-butyne and (Z, E)l-bromo-5,8-undecadien-2-yne followed by semi-hydrogenation of the resultin