3-Phenyl-3-chloro-2-propenthial as Intermediate in the Hydrothiolysis of Dimethyl(3-phenyl-3-chloro-2-propylidene)ammonium Perchlorate. -During hydrothiolysis of the title perchlorate (I), 3-phenyl-3-chloro-2-propenethial is formed intermediately which cannot be isolated neither in pure form nor as
β¦ LIBER β¦
Conformational analysis of the Favorskii rearrangement using 3(a)-chloro-3(e)-phenyl-trans-2-decalone and 3(e)-chloro-3(a)-phenyl-trans-2-decalone
β Scribed by Vickers, Stanley; Smissman, Edward E.
- Book ID
- 125953769
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 492 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The threeβdimensional structure of the title compound has been established by means of an Xβray analysis. The product was formed by a thermal 1,3βdipolar cycloaddition. According to the concerted [~Ο~4~__s__~ + ~Ο~2~__s__~]βmechanism the formation of this stereoisomer should actually be