✦ LIBER ✦

Conformation of zearalenone in solution: A vicinal coupling constant and molecular mechanics study

✍ Scribed by Luis Muñoz; Ricardo Riguera

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 332 KB
Volume: 28
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260280802

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✦ Synopsis

Abstract

Vicinal coupling constants of stereochemical significance were obtained in four solvents for zearalenone and specifically deuteriated zearalenone. Comparison with values calculated for several conformations using molecular mechanics calculations indicates that zearalenone exists in a single conformation in solution. The solvent dependence observed for the H‐9′ and H‐10′ signals cannot be attributed to a conformational equilibrium.

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