## Abstract The conformation of the ethoxy tail flanking the cyanobiphenyl core has been studied in the liquidโcrystalline phase as well as in the isotropic solution. In solution, the vicinal coupling constant ^3^J~CH~ for the moiety C^ph^O๏ฃฟCH (C^ph^: phenyl carbon) provided the information regardi
โฆ LIBER โฆ
Conformation of 1,3-dimethoxypropane in the gas phase and in solution: rotational isomeric state simulation of NMR vicinal coupling constants
โ Scribed by Akihiro Abe; Noriko Ichimura; Tetsuo Shinohara; Hidemine Furuya
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 420 KB
- Volume
- 350
- Category
- Article
- ISSN
- 0022-2860
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The complete analysis of the 'H NMR spectra of [ (C,Me,)lr(glycinate)CI] and [ (C,Me,)Ir(N-methyl-g1ycinate)Clj provide information for the conformational analysis of the five-membered N-C-C-0-Ir ring. A Karplus relationship has been established for these metallacycles [ 3J(H,H) = 8.9 cos' 4 -1.0 c