How many conformers of the 1, 2, 3-propanetriol triacetate are present in gas phase and in aqueous solution?
✍ Scribed by Dimitris G. Papageorgiou; Ioannis N. Demetropoulos; Isaac E. Lagaris; Panos T. Papadimitriou
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 539 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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The conformational stability of aminomethanol and its methylated derivatives has been investigated by means of ab initio methods in the gas phase and aqueous solution. Among the computational levels employed, HF/6-31G \* \* //HF/6-31G \* \* calculations correctly describe the conformational features
## Abstract EPR Spectra have been measured for aqueous solutions of a series of Gd^3+^ complexes at variable temperature and a range of magnetic fields; S‐band (0.14 T), X‐band (0.34 T), Q‐band (1.2 T), and 2‐mm‐band (5.0 T). The major contribution to the observed line widths is magnetic‐field‐depe