Conformation and configuration of diastereomeric phosphine oxides
✍ Scribed by Charles A. Kingsbury; David Thoennes
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 180 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The conformational analysis and the assignment of relative configurations [(__RR__, __SS__) and (__RS__, __SR__)] to the dia‐stereomeric racemates of two acyclic ketones with two asymmetric carbons, ±‐2,2,7,7‐tetramethyl‐5,6‐diphenyloctan‐3‐one and ±‐5,5‐dimethyl‐1,3,4‐triphenylhexan‐1‐
Structural assignment and conformational features of two diastereomeric oxidation products of 2@deoxycytidine, the 5S\* and 5R\* diastereomers of N1-(2-deoxy-b-D-erythro-pentofuranosyl)-5-hydroxyhydantoin were achieved by combining NMR studies and restrained molecular dynamics. Interproton distances