Confirmation of the structure of ceriperol and its related sesterterpenes by the total synthesis
β Scribed by Shigeki Fujiwara; Mario Aoki; Tadao Uyehara; Tadahiro Kato
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 258 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The dl-synthesis of the revised formula of ceriferol and ceriferol-I was achieved, leaving no doubt that the revised structure has been correctly formulated.
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CCHPAVEHINE, C2CH2504N. m.p. 138'. was isolated from Corvdaliq aurea Willd. by Manske in 1938 (1) and assigned as (i) by chemical methods (2). Kametani, & & (3) recently revealed that the
The trinor-guaiane seaqoiterpnoid(f)-dietmmrol 2 waa synthesized, in only6 steps,fromphotoadduct 5. Thecrucialsteprevolveda Smkmediatedtandemfree radical fragtnentation/elitnination reactionof diiodide10. Support for the resentlyrevisedstructure ofdictamnol is presented Q 1997ElsevierScienceLtd.