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ChemInform Abstract: Total Synthesis of Adalinine: Confirmation of Its Structure.

โœ Scribed by F. BROEDERS; J. C. BRAEKMAN; D. DALOZE


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Facile Total Synthe
โœ Naoki Yamazaki; Toshimasa Ito; Chihiro Kibayashi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Facile Total Synthesis of (ยฑ)-Adalinine. -Allylation of cyclic N-acyl-N,O-acetals using a combination of allylsilane and Lewis acid provides a useful construction of 6,6-disubstituted 2-piperidones. Compound (VIII) can be readily converted to the ladybird alkaloid (X) mentioned in the title. -(YAMA