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Total Synthesis of (±)-Dictamnol by a Free Radical Fragmentation/Elimination Sequence. Confirmation of its Revised Structure

✍ Scribed by Gordon L. Lange; Alexandru Merica; Melerin Chimanikire

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
376 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The trinor-guaiane seaqoiterpnoid(f)-dietmmrol 2 waa synthesized, in only6 steps,fromphotoadduct 5. Thecrucialsteprevolveda Smkmediatedtandemfree radical fragtnentation/elitnination reactionof diiodide10. Support for the resentlyrevisedstructure ofdictamnol is presented Q 1997ElsevierScienceLtd.

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