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Confirmation of the Structure of (3 S )-3-Hydroxyquinine: Synthesis and X-ray Crystal Structure of Its 9-Aceto Analogue

✍ Scribed by Srirama Sarma, P. V. V.; Han, Dongmei; Deschamps, Jefferey R.; Cook, James M.


Book ID
126068551
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
83 KB
Volume
68
Category
Article
ISSN
0163-3864

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Synthesis and X-ray crystal structure of
✍ Olivier Pons Y Moll; Thierry Le Borgne; Pierre ThuΓ©ry; Michel Ephritikhine πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 68 KB

Reaction of pentaerythrityl tetrabromide with fluorenyl potassium gave the title compound in 53% yield. The crystal structure revealed that in this unique trispiro[4.1.1.4.1.1]pentadecatetraene derivative, the adjacent rings are planar and orthogonal.