๐”– Bobbio Scriptorium
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Condensed phase photoelectron asymmetry

โœ Scribed by R.F. Davis; S.D. Kevan; B.-C. Lu; J.G. Tobin; D.A. Shirley

Book ID
103016283
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
308 KB
Volume
71
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Large duectronal asymmetries were observed m photoelectron drstributions from core and valence levels m metals and adsorbate atoms. Intensrues vaned by factors up to 25 as the angle between A and p was vaned. The energy dependence of asymmetry showed atomrc behavror srmllar to that expected for free atoms, modified for the tendencyp IIA.

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The photoelectron emission threshold energy E, of a solute is related to its photoosidation threshoId energy IS by the following correlation: Et = fs -P\_ -170, where Vo is the solvent conduction band depth and P\_ = -(e\*/2r)(l -DLi) is the polarization energy of the mobile electron with r derived